Monday, September 30, 2019

Training Day: Management Analysis

Michael Rounsavall 1/9/08 Management 202 Training Day: Movie Analysis The movie Training Day starring Denzel Washington,proved to show many interesting outlooks of managing activities and skills that I have never even came close to noticing before. Alonzo Harris played by Denzel in the movie expressed many forms of management throughout this movie. He displayed different basic management functions, fundamental management skills, parts of the evolution of management, and also some other key management terms. Jake Hoyt, who Alonzo is supposed to give in an evaluation on, also shows many different forms of management throughout this movie. The first thing I noticed during this movie was the basic management functions that Alonzo was planning throughout the whole movie to achieve a certain goal. At the beginning of the movie I noticed that Alonzo took the drugs from the dealers instead of arresting them. As the movie went on this pattern continued, and it wasn’t until Alonzo sat down with the three police officers that I realized what was actually going on. This meeting was a form of bureaucracy (Griffin, 15), because the top dog police officers, who I thought of as the top managers set a set of guidelines for Alonzo, and allows him to go cash in on Roger’s money stash. At this point I realized throughout the movie I realized Alonzo was displaying basic management functions throughout this entire movie. He obviously had a goal, which was get enough money to save himself from the Russians. He then began planning, and deciding the best way to achieve these goals. (Griffin, 9). This plan consisted of going around and stealing from the drug dealers then selling it for one hundred percent profit or Illegally searching homes for money, when that didn’t work he got permission from the top ranks to steal from his friend Roger. Alonzo then began to organize his plan by getting the people he needed, and determined how each activity and resource would be demonstrated during this robbery. (Griffin,9) This plan was to frame the murder of Roger to look like he had shot a cop, then to steal Roger’s money which would save Alonzo. Alonzo did a spectacular job of leading the group so that it would seem like it was an act of self defense towards Roger. He was barking out orders, and made everyone work together, so that there would be no problem getting away with this (Griffin, 10). After the money was taken by Alonzo he displayed the final step which is controlling. During this stage you must ensure that your firm is going to arrive at its destination at the appointed time. (Griffin, 9) For Alonzo this met he had to get the money to the Russian’s, and he saw Jake as a problem. To ensure that he would reach his final destination Alonzo set Jake up to be murdered, but this didn’t work out because Jake saved the murderers sister. After this Jake realizes that Alonzo is very corrupt, and goes to take back what Alonzo has stolen. This movie not only displayed the basic management functions but also proved to show fundamental skills and other key terms. During this movie I definitely thought of Jake as more of a first line manager who was able to control the streets, but was under the wing of Alonzo and the top executives. Throughout the movie Jake showed just about every one of the fundamental management skills you could show. He definitely possessed the technical skills because he was able to show all the skills necessary with being a cop, especially when he had to fight of f the two rapists (Griffin, 10). He showed most of the other skills at the end of the movie when he was going to take down Alonzo. After Jake escaped from the â€Å"set up†, that Alonzo had planned out for him,he made his own theory about what he was going to do. In management a theory is organizing knowledge, and providing a blueprint for action (Griffin, 12). Jake realized that he gained the respect from Alonzo’s administration in which he controlled, and planned to sneak in Alonzo’s house to take the money back from that he had stolen. As Jake got into Alonzo’s house he showed very good communication skills with Alonzo’s son ensuring his safety, while making sure Alonzo wasn’t able to hear him come in, and conveyed his message effectively so that he could take care of the situation (Griffin, 11). After this Jake was able to take down Alonzo until they were outside, and Alonzo had all of his administration together. Alonzo ran a form of administrative management throughout the projects, where he organized, lead, and controlled what went on, and how the operations were going to take place (Griffin, 15). As Alonzo’s organization realized how corrupt he really was, just like many higher level managers are accused of, they stopped letting Alonzo control them, and allowed Jake to take Alonzo’s stolen money for evidence. Jake definitely was not interested in the human ethics movement whereas that workers respond social context of the workplace(Griffin, 15). Jake did a good job proving that he was very ethical throughout this movie, and proved he was ready to move up to a higher position. Even though Alonzo did a good job displaying management skills, he was very corrupt, and was cheating his way through the system. This movie showed how people could control an administration, but be shut down for doing things the non-ethical way. Jake fought through this corrupt system, and showed great fundamental managementskills throughout this entire film. I never realized how much this film actually showed related to the world of management until I really looked closely at it. I’m sure now that I will be able to look at films such as this one, and be able to understand how they also have to do with managing a company. York, 2006.

Sunday, September 29, 2019

Employment and labor scenarios

Prospective Risk Management Identify and describe strategies you could adopt to limit legal risk in this area in the future. Be prepared to address any questions the committee may have. Identify and describe strategies you could adopt to limit legal risk in this area in the future. Hiring panel/ interview panel Suggest a hiring panel or an interview panel. To minimize the possibility of such a scenario happening In the future, a strategy just be developed that requires the Involvement of several relevant resources.These resources Include the human resources department and other managers. Communication, education, and reporting must be Integrated In a plan that successfully nameless the chance of recurrence. We suggest a hiring panel that consist of a human resource manager, hiring supervisor, recruiter, and departmental representative. These members will make up a hiring panel that spread the responsibility of ethics in making hiring decisions. Human resource review Recommend human r esources review all hiring decisions before they are final.Require documentation regarding hiring rationale Suggest that documentation be required explaining rationale for all decisions. A decision to hire or not hire a candidate should be based on qualifications and attributes that are attractive to the hiring organization. Managers make sound decisions in their hiring choice should be able to document rationale. This may materialize as a standard document consistent throughout the organization or as a aroma correspondence supporting the hire of a candidate among the hiring panel.This type of documentation may also serve as a tool to defend an organization or manager in cases like scenario C. Continuing education Promote frequent education of best hiring practices and enforceable laws. The goal of continuing education on hiring practices within the organization is meant to ensure that all affected personnel are aware of best practices, current trends, and laws relevant to hiring. E ducation should Include the Call Rights Act, delimitation scenarios, and related call cases.It Is suggested here that organizations use computer training modules to update and refresh members of the organization on a departments in staff meetings. There should be a way to account for the comprehension of education material. Methods include post educational tests from computer models and statements of attendance and understanding in meetings. Apply the four principles of ethics to hiring practices. Suggestions: Have mediators or arbitrators ready for situations like this.

Saturday, September 28, 2019

7 Essential Checks to Make Before Ditching Your Old Phone

7 Essential Checks to Make Before Ditching Your Old Phone It’s the season for the giving and receiving of gifts, and whether someone else has generously bought you a smartphone or you’ve decided to treat yourself, it’s time to bid farewell to your old handset and face the future with your new one. But wait—we’ve got a few checks you need to make first. we’re not going to cover the entire procedure of exchanging telephones here, and fortunately it’s a considerable measure less demanding than it used to be because of the reinforcement includes now incorporated with Android and iOS, and applications, for example, Google Photos. Rather we will hail seven things you won’t not have acknowledged you have to consider. Your two-factor codes Two-factor verification is a standout amongst the most essential and viable safety efforts you can set up on your different records, yet it means you’re depending on your telephone to produce codes to sign in to applications, for example, Gmail on new gadgets. Now and then codes get sent by means of SMS and here and there you require a validation application, yet in either case, ensure you’re not depending on your old telephone when you dispose of it. On account of SMS that implies swapping your SIM card or refreshing your portable number in your different record pages. For code-creating applications, check the directions inside the application and inside your records for points of interest of how to get everything moved to another telephone. Your chat histories With such a large number of moment emissaries doing the rounds now, it can be anything but difficult to neglect to take the majority of your discussions with you when you switch telephones (in the event that you need to that is—perhaps you’d rather begin with a fresh start). For some applications, as Facebook Messenger and Instagram Direct, everything basically returns when you sign into the significant application on your new telephone. For different applications, it’s not all that direct, so it’s worth twofold checking. In WhatsApp, for instance, you have to go to Chats and Chat reinforcement from the Settings passage in the application menu. Instant messages can be somewhat baffling to spare and reestablish. On iOS, They’re incorporated into the iCloud or iTunes reinforcement you should’ve set up; on Android, pretty much the best application we’ve found for the activity is SMS Backup+. In case you’re exchanging amongst Androi d and iOS, you can trade your writings to protect them for descendants, yet you there’s no real way to stack them move down on your new telephone. Your browser data You probably don’t give much thought to the stuff you’ve been doing in your browser on your smartphone—your new phone will come with one preinstalled, and installing third-party ones is straightforward—but you might just want to double-check that you are taking with you everything you need. For Android that includes files you might have downloaded to your device, which you can look up by loading up the Settings app then tapping Storage, Files, and Download(or by using the third-party file manager of your choice). Browsers on iOS can’t directly download files (except photos) to storage, so there’s nothing to worry about there. Make sure your browser is syncing all your data like passwords and browsing history too, if you want to bring this all up on your new phone: On Google Chrome find the Settings entry in the menu then tap your Google account at the top. On Firefox for mobile, again the sync and sign-in option is the top one on the Settings screen. Your local files Such an extensive amount our stuff sits in the cloud now thus numerous applications pull all that they require from the web that it’s anything but difficult to disregard the documents that may get left behind. Luckily both Android and iOS now incorporate restricted document chiefs of their own, however there’s no simple approach to check You’ve found everything before you wipe your telephone. On iOS, just tap the Files application, and on Android, go to Storage at that point Files from the Settings application. Search for envelopes made by applications that may not really be incorporated into reinforcements: Think about podcasts, for instance, or information spared by your wellness or rest following applications on your telephone. Photographs and recordings were presumably first at the forefront of your thoughts for what to exchange over to your new gadget, however is your photograph and video reinforcement device of decision finding everything? Consider screensh ots (on the off chance that you need them) and pictures sent to your moment errand person applications (on the off chance that you need them). Your gaming high scores With any favorable luck, the diversions you’re playing will shield your high scores and bring them back when you sign into similar applications on your new device, however this isn’t by and large the case, especially for entertainments that don’t use the structures gave by Apple and Google. All that you can really do in this condition is check with the fashioner or the diversion’s assistance pages to see what the situation is, and charge or extra your present progress and high scores if you need to. Again, you might be in a tight spot in the event that you’re trading among iOS and Android, and will probably need to buy the preoccupation again also, if it’s not free. A program like iExplorer ($39.99 for Mac or PC) or Helium (free for Android) may have the ability to help anyway it depends upon how the entertainment has been set up and how open its records are. The redirection planner may moreover have the ability to give you more information. Your registered devices Some applications, as Spotify and Google Play Music, put a farthest point on the quantity of gadgets you can use without a moment’s delay, or if nothing else download disconnected substance to on the double. Gone through the applications on your old telephone and check whether this could apply to anything you have. More often than not deactivating your old gadget won’t expect you to really have the gadget with you, however it’s smarter to be protected than too bad. In the event that you can sign out and uninstall the application at that point do as such. Truth be told, experiencing your applications one by one and uninstalling them is a decent method for checking you haven’t missed anything. Apple additionally prescribes you deregister iMessage in case you’re moving to an Android telephone to ensure you can get SMS and MMS messages on your new gadget. You would now be able to do this without your unique iPhone, yet the deactivation may be postponed. Your smart home controllers In case you’re utilizing your current telephone to deal with your shrewd home then you need to ensure control has been effectively exchanged to your new telephone before you discard your old one, else you could have your savvy lights driving you on a cheerful move each night with no real way to turn them off. Luckily, equipment creators realize that individuals change telephones every once in a while, and for the most part make the procedure entirely effortless, particularly in case you’re dealing with your gadgets through HomeKit or the Google Home application. Be that as it may, it’s as yet worth ensuring the pertinent applications are up and running on your new telephone while despite everything you approach similar settings on the old one. In case you’re confounded or something doesn’t exchange over appropriately, your best port of call is the producer

Friday, September 27, 2019

Contemporary issues in marketing Essay Example | Topics and Well Written Essays - 2000 words

Contemporary issues in marketing - Essay Example Business and promoting analysts direct the greater part of consumption examination to all the more correctly comprehend consumer inspirations and figure out what items consumers will purchase. To date, consumption is understudied in social science. Early social scholars treated consumption as a bit of hindsight. Marx (1972) alluded to consumption as an "item fixation," a social need that came about because of the investor mode of processing. Weber (1958) in his dissection of the "Protestant ethic," proposes that overconsumption is connected to indulgent propensities. Simmel (1997) prominent that form, shopping and mass consumption are strategies for self representation in current urban life. Furthermore, extensively, Veblen (1959) created the idea of the "relaxation class," where consumption is utilized to mean high social standing and class. Contemporary sociological examinations concerning consumption practices start with Bourdieu’s (1984) idea of "social capital," which clarifies how people utilize consumption to exhibit economic wellbeing and Ritzer’s (1996) hypothesis of the " Mcdonaldization of public opinion," where he contends that cutting edge consumption is supported by substantial enterprises. All the more as of late researchers are progressively examining non-monetarily judicious consumption drills. A subset of consumer’s utilization obtaining choices to help issues they feel decidedly about, and in a few cases use consumption as a political apparatus (Michelleti 2003). These consumers, who make non-monetarily reasonable obtaining choices to help social issues, are taking part in ethical consumption (Pelsmacker, et al. 2003; Tallontire, et al. 2001). The investigation of ethics has a long history, starting with exemplary works like Aristotle’s Nicomachean Ethics (350 B.c.e.)[2002] about whether, subfields of ethics

Thursday, September 26, 2019

Economic Nature of the Construction Industry Assignment

Economic Nature of the Construction Industry - Assignment Example Later on, Karl Marx introduced his ideas of exploitation of labor by capital and concluded that the huge constructions that the economy witnessed were all the result of labor that were unjustly and unethically denied the fruits of their efforts which were usurped by capitalists. With progress of time, came the Great Depression and the development of a radically new approach to macroeconomics by John Maynard Keynes. Faced with gloomy prospects of an ever deepening economic depression where the roaring economy of United States that was confident that good times will last forever suddenly faced a scary scenario where jobs vanished and with it the much vaunted purchasing power of populace, Keynes had to think of an way out of that desperate situation. He realized that increasing aggregate demand was the only way out and chose construction industry as the most convenient vehicle of autonomous investment to undertaken by the US government. He prescribed large doses of investment by the gov ernment in construction industry that would, through multiplier effect, generate substantial aggregate demand and consequent rise in general price level that would be sufficient to motivate producers to undertake induced investment. Once this process gets started the upward moving price-wage spiral would pull the entire economy out of the depths of depression. Construction industry is seldom characterized by cutting edge innovations. Any new technique implemented by a builder is quickly replicated by competitors and generally all firms in the industry have access to similar technology. Thus it is an industry that experiences intense competition among equally formidable rivals. It is also an industry where production cycle is possibly the longest and with huge potential for employment requiring substantial levels of continuous investment to keep the industry healthy, construction industry becomes one of the benchmarks for judging the overall

CONTROVERSIAL CURRENT PSEUDO-SCIENCES Essay Example | Topics and Well Written Essays - 500 words

CONTROVERSIAL CURRENT PSEUDO-SCIENCES - Essay Example Ruppetts in 1951 – 1953, in his role as Director of the U.S. Air Forces’ ‘Project Blue Book,’ whose mandate was to investigate reports of UFOs. A UFO may be defined as, Hyneck categorizes UFO experience into nocturnal lights, daylight discs, radar, CE-1: Close Encounters of the First Kind, which include observation at close quarters, CE-2: Close Encounters of the Second Kind, with reported physical evidence, such as ground traces and electromagnetic effects, CE-3: Close Encounters of the Third Kind, in which both objects and occupants are reported and CE-4: Close Encounters of the Fourth Kind, which denotes reported abductions by aliens. (Berliner, UFO Evidence). Whatever may be the status of Ufology itself, it is an undisputed fact that â€Å"UFOs are arguably the most widely reported unexplained mysteries of this or any other century† (Stacy, UFO Evidence). As supported by Gallup polls, Ufology remains the pseudo-science with the largest number of adherents: 70% of Americans profess to believe in UFOs. The believers contend that even if the vast majority of reported sightings of UFOs are subsequently identified or traced to hoaxes or psychological phenomena, there still remains a substantial 25% of sightings which cannot be explained away. Another basis of their argument is that UFO sightings have, by and large, been reported by witnesses usually perceived as reliable: air force and airline pilots. A third contention is that UFO reports all exhibit a certain consistency of character: the objects are symmetrically shaped as spheres, cylinder or discs, all of which do not qualify for optimum aerodynamics in human terms; they travel at incredible speeds which no known aircraft has yet reached; they are luminescent; they emit invisible radioactive energy; they interfere with electrical systems; they emanate odors of ozone or formaldehyde; they are solid, with no obvious aerodynamic features. These supporters discount the commonly held

Wednesday, September 25, 2019

Embodying the Characteristics of Great Leaders Essay

Embodying the Characteristics of Great Leaders - Essay Example From Robert’s perspective on leadership, a leader should make serving a mandatory requirement to ensure that other people’s needs and priorities are adequately met. Spears and Lawrence (2004) shed light into understanding the concept and philosophy of servant leadership. Spear’s essay centers on the development of the philosophy of servant leadership and the characteristics that a servant leader is required to possess. They include listening. A servant leader listens to what others have to say. A servant leader should have empathy and healing (Spears and Lawrence, 2004). A servant leader should be one who is in touch with the feelings and needs of the ones he comes into contact. In addition, a servant leader should be persuasive and aware of the prevailing situations around. Conceptualization and foresight are indispensable to any servant leader (Spears and Lawrence, 2004). Lastly, a servant leader should be committed to the growth of other people and building the community. A servant leader should be a steward of others. It is evident that servant leadership is a concept of humility that shy away from the ego. In addition to having all the above characteristics, Kouzes and Pozner (2007) advise that leadership and challenges go hand in hand. The leadership challenge entails how a leader can integrate various individuals with varying egos and beliefs to work and deliver results for an institution. Leadership entails how a leader can influence a climate that enables people to change challenging situations into a remarkable success. The closest I come to see the philosophy of servant leadership in action is in the South African iconic leader, Nelson Mandela. I like Mandela due to the remarkable leadership qualities that he possessed (Okoth-Okombo & Community Aid International, 2011). In his fight for apartheid, he was a visionary and had a

Tuesday, September 24, 2019

Proposal For 2020 World's Fair Theme Term Paper Example | Topics and Well Written Essays - 500 words

Proposal For 2020 World's Fair Theme - Term Paper Example After every five years, World Expos is carried out for about six months and attracts millions of guests. Sources indicate that among countries that placed their bids to host the 2020 World Expo such as Dubai, Russia, Turkey, Brazil, United Arab Emirates, and Thailand, Dubai has the best chances of winning the bid (Sukhdey 75). This is because Dubai’s bid is the best funded and the most ambitious plan that will change totally vacant desert regions to oasis. Dubai has also spent a lot of money to corral talent from all over the world to plan for its bid. The information in this proposal is need because it details the theme of the 2020 World Expo: â€Å"Connecting Minds, Creating the Future.† The proposal also indicates how beneficial the 2020 World Expo will be to Dubai. This proposal specific information about the 2020 World Expo, some of which include the location of the Exposition, the theme of the exposition, the current situation of the World Expo and the benefits of the Exposition, how the theme will appeal to the public, and how the theme will be evident in the fair. The International Exhibitions Bureau has evaluated the potential of Dubai to host the 2020 World Fair under the theme â€Å"Connecting Minds, Creating the Future†. This theme is very relevant to the current world’s situation and economic realities. This theme will enable the city to move ahead in terms of infrastructure, growth, and connectivity. The entire world will obviously benefit from the result of the Exposition. This is because in the whole history of the World Fair, structures that later become iconic symbols in the host cities are constructed. For example the 1992 Space Needle in Seattle and the 1889 Eiffel Tower (Sukhdey 79). The 2020 World’s Fair Theme will be evident at the fair itself due to the exhibits that will be available. Due to the location, the

Monday, September 23, 2019

Business Article review Essay Example | Topics and Well Written Essays - 500 words

Business Article review - Essay Example The Department of Labor reported that unit labor costs increased by 1.4% while inflation-adjusted compensation rose to only 0.4 %. The higher rate of increases in productivity relative to the mount in hourly wage indicates that "companies are still able to keep a significant share of productivity gains for themselves and their investors." An implication of this is that companies are able to keep a larger share of their revenue as gross profits which can dampen the possibility of inflation as they allow companies to absorb more costs. However, the article also recognized that as companies have strong pricing power, they are hesitant in absorbing higher input costs but are inclined to pass these costs to consumers. The decline in the number of unemployed is indicative of a strong job market (Whitehouse). The article revealed the interrelation of different macroeconomic variables in the society as well as showed how the economic climate affects the position and decision making of business entities. The concepts such as inflation, productivity, and employment levels which are presently tackled in the class and their relationships are more elucidated and understood in the business article. Theoretically, labor productivity and wages are closely li

Saturday, September 21, 2019

Court Structure in Srilanka Essay Example for Free

Court Structure in Srilanka Essay The Supreme Court is the highest and final court of record, and exercises final civil and criminal appellate jurisdiction. Litigants who do not agree with a decision of the original court, be it civil, criminal, or Court of Appeal, may take the case before the Supreme Court, with permission from the Court of Appeal, or special permission from the Supreme Court. The Supreme Court, however, will only agree to consider cases involving a substantial legal issue. The Supreme Court is composed of a Chief Justice and not less than six, and not more than ten, other judges. Cases that fall under the several jurisdictions of the Supreme Court are exercised, subject to provisions in the Constitution, by a bench of at least three judges of the Supreme Court. Thus different cases may be heard at the same time by several judges of the Supreme Court sitting apart. Appeals of decisions of a High Court Trial at Bar are heard by a Bench of five or more Supreme Court judges. The Constitution provides for temporary restrictions on fundamental rights if national security issues are involved. This determination and opinion of the Supreme Court should be by at least five judges of the Supreme Court, including the Chief Justice, except for in the event of the Chief Justice’s recusal. The Chief Justice’s recusal will result in another judge of the Supreme Court taking the Chief Justice’s place. The Constitutional Council’s approval is not required if the appointment is for a period of less than 14 days. The age of retirement for Supreme Court judges is 65 years. COURT OF APPEAL The Court of Appeal is the first appellate court for decisions of all original courts and certain Tribunals. The Court of Appeal is composed of the President of the Court, and not less than six, and not more than eleven other judges. Many cases at the Court of Appeal are presided over by a single judge. The Court of Appeal hears appeals against judgments of the High Courts. It exercises appellate jurisdiction for the correction of errors in fact or in law at a High Court, or any Court of first instance, or Tribunal, or other Institution. In addition to the jurisdiction to affirm, reverse, correct, or modify a judgment, the Court of Appeal may give directions to a Court of first instance, Tribunal, or other Institution, or order a new trial, or order additional hearings as the Court of Appeal deems appropriate. â€Å"Even when there is no right of appeal from a particular court or tribunal, [the Court of Appeal] can exercise [its] powers of ‘revision’ and quash the original court’s or tribunal’s order [based on] an error of law apparent [in] the record.† 1The Court of Appeal, if appropriate, also has the authority to issue a ‘stay order’ and suspend proceedings in a lower court until the revision application is heard and determined. The Court of Appeal also has the authority to receive and admit new evidence additional, or supplementary, to evidence already recorded in a court of first instance. Appeals of judgments, sentences and orders at a High Court Trial at Bar are forwarded directly to the Supreme Court by virtue of the Code of Criminal Procedure (Amendment) Act, No.21 of 1988. The Court of Appeal, in exercising its power to examine and reverse a judgment of any court of first instance, has the authority to examine any record of any court of first instance. The Court exercises jurisdiction to grant writs of habeas corpus in order to bring before the Court a person who has to be dealt with according to the law, or to bring before the Court a person illegally or improperly detained in public or private custody. Court of Appeal cases are now published in Sri Lanka Law Reports. As of October 2012, Court of Appeal cases from 1809 through 2005 are accessible online. See section on Cases, Bills, and Acts. HIGH COURTS Trials at a High Court are conducted by the State (Sri Lanka), through the Attorney-General’s Department. The Attorney-General’s Department prosecutes on behalf of the State. Murder trials and various offenses against the State are tried at the High Court; other criminal offenses are tried at a Magistrate’s Court. While some High Court trials will have a jury, some trials will not have a jury. The types of cases that require a jury are provided in the Second Schedule of the Judicature Act No.2 of 1978. Also, the Attorney-General has the authority to determine whether a case that does not fall into a category provided in the Second Schedule of the Judicature Act No.2 of 1978 should nonetheless have a jury. The Penal Code stipulates the types of cases argued in a High Court: â€Å"The Penal Code defines most of the criminal offenses known to our law. And the Code of Criminal Procedure Act. No: 15 of 1979 sets out which of these offenses [can be tried] by each court [High Court and Magistrate’s Court].† The High Court is composed of not less than ten and not more than forty judges. This Court sits in 16 provinces in the country (16 High Courts). Judges of the High Court are appointed by the President of the Republic on the recommendation of the Judicial Service Commission, and in consultation with the Attorney-General. The President of the Republic, acting on the advice of the Judicial Service Commission, exercises authority in disciplinary matters concerning the High Court judges. The President may terminate the service of a High Court judge on the advice of the Judicial Service Commission. The Judicial Service Commission (JSC) was established by the enactment of Article 111D of the Constitution, incorporated by the 17th Amendment, which became effective on October 3, 2001. The JSC is composed of the Chief Justice (as Chairman) and two other judges of the Supreme Court appointed by the President of the Republic. The age of retirement for High Court judges is 61. 4. DISTRICT COURTS District Courts are the Courts of first instance for civil cases. District Courts have jurisdiction over all civil cases not expressly assigned to the Primary Court or a Magistrate’s Court. Sri Lanka has 54 judicial districts. Every District Court is a court of record and is vested with unlimited original jurisdiction in all civil, revenue, trust, insolvency and testamentary matters, other than issues that are assigned to any other court by law. Certain specific civil issues handled by the District Courts include: i. Cases related to ownership of land. ii. Action by landlords to eject tenants. iii. Action to recover debts of more than Rs. 1,500. iv. Action in connection with trademark and patent rights, and infringement of copyright laws. v. Claims for compensation of more than Rs. 1, 500 for injuries caused by negligence. vi. Divorce cases (Formerly, divorce cases were handled by the now defunct Family Courts). Judges of the District Courts are appointed by the Judicial Service Commission (See section on High Courts for information on the JSC). The JSC has the power to dismiss and maintain disciplinary control over the District Court judges. The retirement age for District Court judges, generally, is 60 years. 5. MAGISTRATE’S COURTS The Magistrate’s Courts are established under the Judicature Act, No.2 of 1978. Each Judicial division has one Magistrate’s Court, and there are 74 judicial divisions in Sri Lanka. Each Magistrate’s Court is vested with original jurisdiction over criminal offenses (other than offenses committed after indictment in the High Court.) In cases involving criminal law, the Magistrate’s Courts and the High Court are the only Courts with primary jurisdiction. The respective domains of these Courts are detailed in the Code of Criminal Procedure. Appeals from these courts of first instance may be made to the Court of Appeal and, under certain circumstances, to the Supreme Court, which exercises final appellate jurisdiction. The vast majority of the nation’s criminal cases are tried at the Magistrate’s Courts level, which forms the lowest level of the judicial system. Cases may be initiated at a Magistrate’s Court by any police officer or by anyo ne else making an oral or written complaint to the Magistrate. The Magistrate is empowered to make an initial investigation of the complaint, and to determine whether his or her Court has proper jurisdiction over the matter, whether the matter should be tried by the High Court, or whether the matter should be dismissed. If it is determined that the Magistrate’s Court has the proper jurisdiction over the matter, the prosecution may be conducted by the complainant (plaintiff), or by an officer of the Government, including the Attorney-General, the Solicitor-General, a state counsel, or any officer of any national or local government office. At the trial, the accused has the right to call and cross-examine witnesses. Trials are conducted without a jury, and the verdict and sentence are given by the Magistrate. Any party in a case who is in disagreement with a judgment has the right to appeal the judgment, on any point of law or fact, at the Court of Appeal. If the police decide not to institute criminal proceedings in a Magistrate’s Court, the complainant has the option of filing a private plaint, and the complainant may retain an attorney for this purpose. As indicated earlier, while murder trials and various offenses against the State (Sri Lanka) are tried in a High Court, other criminal offenses are tried in a Magistrate’s Court. The Penal Code defines which court, a Magistrate’s Court or a High Court, has the necessary jurisdiction (Code of Criminal Procedure Act No.15 of 1979). If a new offense is codified by law, for instance the Prevention of Terrorism Act, the relevant statute will indicate the manner of trial. The Magistrate’s Courts are ordinarily empowered to impose the following sentences: A fine of up to Rs. (rupees) 1,500.00, and/or two years of rigorous or simple imprisonment, unless special provisions vest the Magistrate’s Courts with the power to impose higher penalties. Magistrates are appointed by the Judicial Service Commission (JSC), and the Commission exercises disciplinary oversight over the judges, including the power of dismissal (See section on High Courts for information on the Judicial Service Commission). The retirement age for Magistrate’s Court judges, generally, is 60 years. 6. PRIMARY COURTS Each Primary Court is vested with the following jurisdictions: I. Original civil jurisdiction over cases involving debt, damages, demands, or claims that do not exceed Rs. 1,500. Ii. Enforcement of by-laws by local authorities and disputes relating to recovery of revenue by these local authorities. iii. Exclusive criminal jurisdiction over cases relating to offenses â€Å"prescribed† by regulation by the Justice Minister. iv. Offenses in violation of the provisions of any Parliamentary Act, or subsidiary legislation, that is related to jurisdiction vested in the Primary Courts. The Primary Courts are established under the Judicature Act, No.2 of 1978. There are seven Primary Courts: One each in Anamaduwa, Angunukolapelessa, Kandy, Mallakam, Pilessa, Wellawaya and Wennappuwa. In all other divisions, the Magistrate’s Court exercises the jurisdiction of the Primary Courts. Requests for revision of orders made by a Primary Court are handled by the High Court in that province. All Primary Court judges are appointed by the Judicial Service Commission (JSC), which is also vested with the power of dismissal of the Primary Court judges (See section on â€Å"High Courts† for information on the JSC). Generally, the retirement age for Primary Court judges is 60. 7. MEDIATION BOARDS The mediation Boards Act of 1995 and subsequent amendments govern these mediation aspects. The Minister has power to set up Mediation Boards and set the areas that will come under such mediation boards. Commercial mediations are reality now in SL.Arbitration ; Is also another form of dispute resolution . Arbitration Act of 1995 and subsequent amendments govern the procedureTribunals- Labour Tribunal established under industrial Disputes Act provides provisions for the employees to institute action against employers.Agricultural Tribunals established under the Agrarian Services Act of 1979 enables settling disputes as to cultivation and related matters.Read Judicature Act , Constitution of Sri Lanka , Books on Legal System about Sri Lanka for further details. Visit website of Minisrty of Justice as well to get current information 8. OTHER COURTS AND TRIBUNALS The other courts include the Kathi Court, the special tribunal that adjudicates on matrimonial matters relating to Muslims. Buddhist ecclesiastical matters that fall under the purview of the Buddhist Temporalities Ordinance of 1931 are heard by the ordinary courts. Disciplinary matters pertaining to Buddhist clergy are handled by religious councils which are under the authority of the Buddhist priests themselves. There are numerous administrative tribunals, such as the Inland Revenue Board of Appeal, The Workmen’s Compensation Tribunals, Labor Tribunals, the Board of Appeal under the Factories Ordinance, Tribunals under Agricultural Productivity Law, Labor Tribunals under the Wages Board Ordinance, etc. Most decisions of these tribunals can be appealed at the Court of Appeal; when regarding a substantial question of law, the decision of the Court of Appeal may be taken up at the Supreme Court. REFERNCE âž ¢ http://www.nyulawglobal.org/globalex/sri_lanka.htm âž ¢ http://www1.umn.edu/humanrts/research/srilanka/legalsystem.html âž ¢ http://www.nationsencyclopedia.com/Asia-and-Oceania/Sri-Lanka-JUDICIAL-SYSTEM.html#ixzz2KPq331RT

Friday, September 20, 2019

Core Context Overview Ratios And Evaluation Finance Essay

Core Context Overview Ratios And Evaluation Finance Essay Kesko Corp is a diversified retail business headquartered in Helsinki, Finland. Founded in 1940, it deals with food trading, logistics, data and network management, building and home improvement alongside agricultural supplies, car and machinery trading. Apart from Finland, the company operates through subsidiaries like Kesko Food, Musta Porssi, Konekesko, Indoor, Intersport in Norway, Sweden, Russia, Lithuania, Estonia, Belarus and Latvia. 2. CORE: Context, Overview, Ratios and Evaluation Context: External Kesko has around 2,000 stores structured as chain operations in parts of Nordic, Baltic, Scandinavian regions. Kesko and K-retailers comprise of K group which employs approximately 45,000 employees with year 2011 turnover stands at â‚ ¬ 12 billion. By 2011, Kesko Corporation has circa 19,000 employees with net-sales around â‚ ¬ 9.46 billion. An increase of 7.8% from last years (â‚ ¬ 8.77 billion). Finnish net-sales rose by 7.3% and other countries operations increased by 10.1%. Main drivers of success were food trade, building, car and machinery business. Earning-per-share of 2011 stands at 1.85 compared to 2.08 in 2010. A dividend of â‚ ¬ 1.2, 65% of the EPS was issued. Keskos market share is 35% and local major competitors are: S-Group (45%) Suomen Lahikauppa International competitor includes: Lidl Internal Kesko is controlled by its shareholders. Shareholders elect the Board of Directors and Auditor. Kesko Group is managed by the Board and the Managing Director who is also the President and CEO. CEO and President are selected by the Board of Directors. The company has Corporate Management Board having 7 members that control different divisions and responsibilities of the group. All Kesko Board members are non-executive directors. In 2011 it was decided by the Board that all of its members are independent of its companys shareholders. The Board ensures that the companys administration, operations and accounting as well as financial management controls are in place. Shareholding as below: The companys share capital is â‚ ¬ 197.2m. Total number of shares is 98.6m of which 31.7m are classed as A shares and 66.9m are B shares. Share A carries 10 votes and Share B one vote. Key group strategies include: Growth in Russian Regions Investment in development of store network Development of e-commerce Healthy profitable growth and increase shareholder value. All in all Keskos capital expenditure in growth stands at â‚ ¬ 425m in year-2011. Six new K-citymarket stores, 17 K-supermarkets in food business, 4 new K-rauta stores in building and home-improvement, 1 Kodin Ykkonen departmental store. The aim is to open 10 new stores in Russia with approx. â‚ ¬600m expenditure till 2015. Overview: Kesko: YEAR 2011 â‚ ¬m 2010 â‚ ¬m Turnover % Change 9,460 7.8% 8,776 Cost of Sales % Change 8163 8.17% 7546 Operating Profit % Change 281 -8.4% 307 Profit after Tax % Change 197 -8.8% 216 Operating Cash flow % Change 215 -51% 438 Capex % Change 427 30.2% 328 Total Debt (Long + Short term) % Change 400 -16.1% 477 Total number of Employees % Change 18,960 4.1% 18,215 The difference between costs and sales determines the operating profit. Though turnover is healthy, decrease in operating profit can be attributed to increase in cost of sales. Expenses also increased and in totality affected the profit position. Increase in capital expenditure is due to expansion in international markets and machinery which impacted negatively on the cash-flow position. Total debt position decreased which shows a healthy sign of effective use of company resources. Employee number remains constant. Koninklijke Ahold: YEAR 2011 â‚ ¬m 2010 â‚ ¬m Turnover % Change 30,271 2.5% 29,530 Cost of Sales % Change 22,350 3.4% 21,610 Operating Profit % Change 1,347 0.8% 1,336 Net Income % Change 1,017 19.2% 853 Operating Cash flow % Change 1,786 -15.4% 2,111 Capex % Change 881 -21.1% 1117 Net Debt % Change 1,088 47.6% 737 Total number of Employees % Change 218,000 2.3% 213,000 In comparison to Kesko, Ahold is 3 times bigger company as above. c).Ratio Analysis The ratio analysis is made up of performance, working capital, liquidity/solvency and shareholder ratios. Performance ratio is how well the company manages its assets and converts them into revenue and how efficiently converts its sales into cash. The better these ratios are the better value for shareholders. Kesko in comparison with Ahold Performance calculations 2011 2010 Change in 2011 Ahold 2011 Gross margin 2011: 13.7% 14.0% -0.3% 26.17% 1297/9460 2010: 1230/8776 Expenses/sales 2011: 18.1% 18.4% -0.3% 21.72% 1721/9460 2010: 1622/8776 Net margin* 2011: 2.9% 3.5% -0.6% 4.45% 281/9460 2010: 307/8776 Asset turnover 2011: 3.6 3.4 0.2 2.92 9460/2565 2010: 8776/2550 Return on 2011: 12.5% 13.9% -1.4% 12.99% Capital 281/2233 employed * 2010: 307/2210 Gross margin has declined because of increase in cost of sales sub-sequentially affecting the net margin. Slightly better asset turnover shows improved sales performance by every â‚ ¬ invested in the given year. Given the retail nature of the business this is normal. ROCE is not a matter of huge concern, however needs to be monitored closely. The ROCE decline could be the reduced profits attributed to shareholders. Ahold on the other hand shows big numbers. From retail perspective, Keskos performance is not bad at all. There are few dips in the numbers which are usual for a transactional retail business. d).Working capital is used to measure the companys short-term financial health. It is also called operational liquidity for the period of 12 months. Positive working capital can prove that the company can pay its short-term liabilities well. Negative working capital will increase the risk of default on short-term liabilities. Keskos working-capital ratios Working Cap Calculations 2011 2010 Change Ahold 2011 Inventory days 2011: 38.8 days 36.6 days 2.2 23.9 (divided by CoS) 867 x 365/ 8,163 2010: 757365/7,546 Debtor days 2011: 27.0 days 25.8 days 1.2 9.1 (divided by 700 x 365/9,460 sales) 2010: 620365/8776 Creditor days 2011: 51.3 days 52.4 days -1.1 39.8 (divided by CoS) 1148 x 365/ 8,163 2010: 1,085 x 365/ 7,546 Some difference year-on-year. Increase in inventory days shows negative cash-flow and control on inventory. Increase in debtor-days is bad for cash hence the cash position. This could be poor collection or price negotiations for discounts. Also seems like customers are taking longer to pay. Early payments to creditors depict the decrease in creditor-days, a virtuous gesture for suppliers but not good for cash. (d).Liquidity and Solvency ratios also a measure of companys ability to pay its short-term obligations also called a Quick ratio. This means that the current assets should outweigh current liabilities to stay positive. It also indicates the companys ability to meet interest payments. Higher the level of capital compared to debt, the lower these ratios are. Liquidity calculations 2011 2010 Change Ahold 2011 Current ratio 2011: 1.33 1.49 -0.16 1.13 2161/1625 2010: 2407/1616 Acid test 2011: 0.80 1.02 -0.22 0.81 2161- 867/1625 2010: 2407-757/1616 Solvency 2011 2010 Change Ahold 2011 Interest cover 2011: 13.40 18.05 -4.65 281/21 4.01 2010: 307/17 Gearing 2011: 0.18 0.21 -0.03 0.56 400/2233 2010: 477/2210 Decrease in current ratio is due to in-efficiencies in debtor and inventory turnover. Shortfall in cash has deteriorated acid test which is more conservative than current ratio. Variation in interest cover is an imminent concern given its retail landscape and possible inability to meet its debt obligations. Keskos cost of sales needs to be addressed to better manage profits sub-sequentially improving its cash reserves to shield the interest-cover shortfall. Decrease in gearing is a positive sign, showing Keskos good portion of equity is in place displaying monetary strength. e).Shareholders and Investment ratios Return on equity is the measure to see how much profit is left for shareholders. Higher this ratio, higher the profit for shareholders. Shareholders can decide to withdraw this profit or keep it invested in the business as retained earnings. Earning per share is a measure of firms profitability. Dividend cover is the number of times a firms dividends to shareholders is paid from its net profits. Higher the cover, more the ability to pay the shareholders. PE ratio measures price compared to earnings. The bigger the earning, more potential of rise in future earnings. Shareholder Calculations 2011 2010 Change Ahold 2011 Ratios 2011: ROE 197 / 2,233 8.8% 9.7% 0.9 17.3% 2010: 216 / 2,210 2011: 1.85 2.08 0.1 0.92 EPS 197 / 99 2010: 216 / 99 2011: Dividend Cover 1.85 / 1.20 1.54 times 1.6 times 0.06 2.30 EPS / Dividend 2010: Per share 2.08 / 1.30 PE Ratio 2011: 24.1 / 1.85 2010: 34.70 / 2.08 13.0 16.82* -3.82 11.48 Low ROE is result of low profit. Debt in the company also affects ROE, but in Keskos case debt has been reduced which might not be relevant for decline in ROE. Keskos increase in intangible assets can also result in low ROE. EPS is declined resulting from decline in operating profit, and possible increase in capital expenditure from last year. But still manageable and shows strong growth potential. Dividend cover is constant but relatively lower than Ahold. PE ratio is declined from previous year. This may show low market confidence in 2011. *http://www.kesko.fi/en/Investors/Share-information/Key-indicators-by-share/ f).Conclusion and Recommendation: Kesko is a strong company with year-on-year growth. However year 2011 has underperformed. The year seems a bit challenging ranging from its high cost of sales and higher volatility in its share price. Given its higher interest payments shows a possibility of higher borrowing costs. Increase in intangible assets (Computer Software, Licences) and expansion cost in the form of CAPEX is also a driver of declining cash-flows. The seasonal nature of operations arising from seasonal fluctuations took a toll on profits which are not earned throughout the year. Depending on Keskos segmental characteristics these profit variations are possible. Kesko Strengths Diversified product portfolio Effective Business model Growth in E-commerce Strong chain support functions Weaknesses High dependency on euro-zone. Lack of skilled labor Foreign exchange risks Changes in the Groups structure by creating a new subsidiary in Russian market and transferring 36 stores to the subsidiary has also affected Keskos performance. Uncertainties in the euro zone, volatility in consumer demand is affecting the appetite for CAPEX in the euro zone. Hence the reason of strong expansion in Russia. E-commerce is booming with international customers creating alternative benefits for Kesko. Future looks favorable for Kesko. Low investment in euro-zone will offset high CAPEX in Russian region. Steady growth in the food business expects to continue. Home and building business is expected to balance against consumer demand. Net sales are expected to grow next year i.e. 2013. All in all the growth-story looks good for Ahold. Ahold has the means to acquire Kesko. However my recommendation would be hold the acquisition desire for now till numbers become promising. As an alternative a 20% shareholding now will be suitable for Ahold. In both scenarios, if Kesko does well in the future, Ahold is sure to benefit from its interest in Kesko. Answer 3: The cash-flows of the project are below: Year 0 2014 2015 2016 2017 2018 Sales Revenue 0 300,000 510,000 680,000 450,000 240,000 Loss of Contribion (35,000) (35,000) (35,000) (35,000) (35,000) Variable Costs (160,000) (240,000) (280,000) (210,000) (140,000) Fixed Costs (22,000) (22,000) (22,000) (22,000) (22,000) Op Cash flow 65,000 195,000 325,000 165,000 25,000 Working capital (70,000) (70,000) (70,000) (70,000) (70,000) Capital Cost (500,000) Residual Value 100,000 Net Cash flow (500,000) 78,000 338,000 598,000 278,000 98,000 Depreciation of 80,000 is not included in fixed costs as it does not affect cash. Head office overheads are also not a constant fixed cost over 5 year period so not including in the fixed costs. The Payback time is approx. 2 years 6 months. Net Present Value calculation is below with discount rate of 15%. Year Cash flow PV Factor PV 0 (500,000) 1.0 (500,000) 1 78,000 0.870 67,860 2 338,000 0.756 255,528 3 598,000 0.658 393,484 4 278,000 0.572 159,016 5 98,000 0.497 48,706 NPV 424,594 NPV is positive, so recommendation to the board is to go ahead with the project With adding back depreciation of 40,000 i.e. 80,000 x 5 at the end of 5 year: Year Cash flow PV Factor PV 0 (500,000) 1.0 (500,000) 1 78,000 0.870 67,860 2 338,000 0.756 255,528 3 598,000 0.658 393,484 4 278,000 0.572 159,016 5 98,000 0.497 48,706 Depreciation (400,000) NPV 24,594 NPV is still positive, so recommendation to the board is to go ahead with the project. The IRR is 43.7%, where NPV becomes zero. Answer 4: Usefulness of Company accounts to assess value of companies Hello friend, In order to understand company accounts, the financial accounting statements provide a representation of financial position and performance of the company. Company accounts are made up of 3 statements: Balance Sheet (aka Statement of financial position) Income Statement ( aka Profit and Loss account) Cash-flow statement Cash-flow statements show how much cash came in or went out in a particular period. For example, I started a business of selling flowers with  £40. On Tuesday morning, I bought flowers worth  £40 and sold three-quarters of flowers for  £45 cash that day. My cash-flow position during Tuesday will look like this: Cash invested by me:  £40 Cash from sales of flowers:  £45 Cash paid to buy flowers: ( £40) Closing balance of cash  £45 Income statements show how much wealth i.e. profit is generated or lost by the company over a period of time. Profit and loss can be defined as increase or decrease in wealth through trading activities. For income statement it shows wealth generated on Tuesday. It represents the difference between the value of the sales made and the cost of goods sold. Sales revenue:  £45 Cost of goods sold (3/4 of  £40) (30) Profit  £15 It is the cost of flowers sold that is matched against the sales revenue to get profit. Not the whole cost of flowers is shown as unsold flowers in my case  ¼ of  £40=  £10 will adjusted against the future sales revenue that it will generate. Balance sheet shows accumulated wealth of the business at the end of the given period. It also shows what form have that wealth taken? For balance sheet the wealth created at the end of Tuesday trading. It will show list of resources held at the time. Cash (closing balance)  £45 Stock or inventory for resale  £10 Total assets  £55 Equity  £55 Equity is the stake of the owner in the business. Where-as assets include cash and stock. Cash is a vital resource for a business to function. It is used to retire debt and or for the purchase of stock. However, reporting cash alone will not portray the health of the business. The changes in cash do not tell us how much profit is generated. Thats why income statements are used. A balance-sheet on the other hand shows total wealth of the business. Cash is only one form in which wealth can be held, however in bigger businesses there are land, machinery and equipment is also classed as wealth in the balance-sheet. A combination of these statements states the financial position and health of the company. The relationship of these statements can be seen by a figure below: Another way to valuing a business is through company assets, price of parallel business and finally the cash-flow. Company assets are appraised to assess their value deducting any liabilities. The sales of similar business are valued in the area of your business. Location is very important in valuing the business though the limitations include undermining the value of your business by management and sales. The most effective way is the liquidity of the business i.e. cash position minus liabilities. You know what is coming your way. Issues: Issues related to these statements are the way they are presented. Use of creative accounting can somehow alter the real picture and position of the company. Audited company accounts are seldom used by investors or potential buyers, primarily for the reason of creativeness. Depending on the nature of your query for valuing the company, apart from simplified company accounts mentioned above, it can vary from share price to ratio analysis to cost of capital or debt and so on.

Thursday, September 19, 2019

a painting that has influenced my view of the world :: College Admissions Essays

a painting that has influenced my view of the world    Select a creative work-a novel, a poem, a musical piece, a painting, or other work of art-that has influenced the way you view the world and the way you view yourself.   Discuss the work and its effect on you.           Ã‚  Ã‚  Ã‚  Ã‚   I still remember the first time I saw her.   Her jealous beauty staring fervently at me.   Her wealth of luscious red hair tamed by a golden clip.   The precious face staring lustfully over my shoulder-or perhaps staring at me?   Soft pearly-white hands poked through a deep green velvet dress-in one hand a violin, the other a bow.   Behind her a brilliant yellow canary rhapsodizes a tune that she pauses to hear.      Ã‚  Ã‚  Ã‚  Ã‚   Her name is Veronica Veronese.   She hangs in the Delaware Art Museum but I first saw her in Art & Antiques, a monthly art magazine.   The whole painting enthralled me so greatly that I decided to learn more about the artist: Dante Gabriel Rossetti.   He belonged to a group called the Pre-Raphaelite Brotherhood: a group of seven united through their art.   Having just read about the superhuman determination and intensity of Michelangelo, these seven were a decided change: they had human faults and error.      Ã‚  Ã‚  Ã‚  Ã‚   As I delved into their world of Victorian romance and poetry I found that everything that happened in their lives happened, not by chance but for a reason. If Lizzie Siddal, Rossetti's wife, had not died at the apex of their long and winding relationship, then he might not have been perpetually inspired to make the extreme beauties that he painted to memorialize her.   The model for Veronica Veronese is Alexa Wilding.   She, as all the women in his later paintings, looks stunningly similar to Lizzie.    Similarly, in my life, I realized that mistakes happened for a reason.   They humbled me, but also gave me a reason not to go do that mistake again: experience.   Experience is the best teacher that I've found.   Touching a red hot stove is far different than knowing not to touch it.   If you do make the mistake of touching it, you'll never again do it-simply because you know the consequences.      Ã‚  Ã‚  Ã‚  Ã‚   After consuming books about the PRB, I realized that I had to know something about art to appreciate it.   I found this out when I began looking at works by Egon Schiele, an early twentieth century art who painted what most would call pornography.

Wednesday, September 18, 2019

Communications Between Parents and Children Essay example -- Communica

Healthy family relationships depend on healthy communications. â€Å"Good communication helps keep a family running smoothly and prevents misunderstandings from escalating into conflict or from being buried unresolved.† (Feiden, 68) There are many ways and times to practice and teach good communication to children. There are many times that without good communication, the parent-child relationship suffers and sometimes ends abruptly. Allen Schwartz, PH.D., states that he knows of â€Å"many cases where children are raised in an atmosphere of dark secrecy about both the matriarchal and patriarchal parts of their families. They grow up with a sense that something must be wrong but fear discussing this with their parents.† (5) Most people have grown up with family secrets, but some secrets can destroy a family. The act of hiding the secret(s) provides an excuse to limit self-disclosure, and reacts negatively on one’s self-esteem. When these become extremely limited or negative, there is an increased chance of a separation and possible ending of the relationship. The end of the relationship could mean that parent and child no longer talk, or they are forcibly separated for their own health in extreme cases. Unfortunately, â€Å"emotional health can be passed down from generation to generation just as easily as abuse and dysfunction,† (Bloch, 7) making such dysfunctions of communications a continu ous process. Sturges writes â€Å"children will learn how to communicate with the world based in large part on how they have learned to communicate with their parents.† (31) Children often learn their communication behaviors not only from what we say but also from our actions. For example, If you tell your child that they can talk to you about anything, but y... ... their minds. It is important for the parent to respect their wishes and let them know that they will be available when the child is ready to talk and that you won’t be judgmental. Let the child tell the whole story before interceding with your thoughts. There are also instances where the child won’t want your opinion; they just want you to listen to their problems. This can be tricky to know whether the child wants your opinion or your ears but if you are actively listening to your child, you will know what it is that they are wanting. Remember, good communication is the heart of everything you do in life. Without good communication skills, things won’t get done properly and could cause hurt relationships. Learning these communication skills begins at home from the day that the child is born and should be continued into adulthood and for the rest of their lives.

The Journey Through The Differences In Relationships in Cold Sassy Tree

The Journey Through The Differences In Relationships in Cold Sassy Tree Dating back to the early 1900’s and all the way through to the present, romantic relationships have been viewed differently. From strict unwritten dating regulations to not having regulations at all, recent generations have become more liberated in making their own decisions. The progressing times have made us become a more accepting society and have caused a decrease in the strong practice of religion and class. Even though differences such as religion and class in relationships were more than an issue they were not always a complete deterrence. In the novel Cold Sassy Tree (1984), Olive Ann Burn's plot focuses heavily on religion and its role in society. Mary Willis Blakeslee, a Baptist, is tried for heresy by the deacons of the Baptist church for marrying Hoyt Tweedy, a Presbyterian. â€Å"The deacons voted to put it in the church records that ‘Mary Willis Blakeslee has swapped her religious birthright for a mess of matrimonial pottage’† (11). After her father Rucker Blakeslee confronted the deacons they agreed to remove the pottage element from the document (11). Although this confrontation with Grandpa intimidated the deacons it didn’t impede them from excommunicating Mary Willis from her â€Å"birth church.† As it ended up she decided to attend the church of her husband, Hoyt Tweedy. As Cold Sassy Tree illustrates, in Georgia in the early 1900’s religion played a major role in marriage decision along with membership to the church. This sort of attention that Mary Willis a cquired was very hard for her to tolerate emotionally. It was important to her to appear respectable to the community. Regardless of this embarrassment caused by the Baptist... ... the level of education problems such as outside gossiping, financial differences, differences in interests, and the decrease in one’s pride can occur. Religion and class are still issues in relationships but members of our generation tend to question them less, yet these issues have never been a complete deterrence to a happy and healthy relationship. As time periods change so do the values and morals of the upcoming generations. As illustrated the younger the generation, the more liberated they become to make their own decisions and mistakes. It is the mistakes that we learn from that teach us life’s greatest lesson. After all, if we never made a mistake how would we know if we are leading a correct life? Works Cited Burns, Olive Ann. Cold Sassy Tree. New York: Dell Publishing, 1984. Accarino, Susan. Personal interview. 20 March 2001.

Tuesday, September 17, 2019

Recycling

One way the US Government could develop an incentive plan that when you take your items to the recycling enter, that you get a receipt showing what you brought and receive points that can be used toward your utility bill. The point system would convert to dollars for this purpose. Many communities have recycling bins that the sanitation department picks up. The point system can be used with these as well. The workers could leave the slip in the bin for the customer. They could also make sure that all communities' sanitation departments issue these bins.Consumers have several choices in how to recycle. You can take it to drop-off centers, curbside collection, and refund or deposit programs. There are three steps in recycling. First step: after collection is done, the recyclables go too recovery facility to be sorted and cleaned. They are then processed into materials that are used in manufacturing. The materials are then bought and sold like any raw materials for production. Second st ep: You will find that most of today's products are manufactured with recycled materials.The most common are paper towels, newspapers, plastic, aluminum, glass soft drink containers, plastic laundry detergent bottles, steel products, car bumpers, cereal boxes, comic books, aluminum cans, egg orators, nails, motor oil, and trash bags. Other ways that the materials are used are using recycled glass in asphalt for paving roads and using recycled plastic in park benches and carpeting. Step three: Most products you buy are now made with recycled material. When shopping you can look on the labels to see if they are.By buying these products, you will help close the loop on recycling. Other things that you can recycle are the wooden pallets that are used in shipping. You can be used in your gardens, people make furniture Tires are used in asphalt and used for shoring up areas of erosion. The overall benefits of recycling is that it will help to reduce the amount of trash and discarded items go to the landfills and incinerators. It will help to prevent pollution and help to not use new raw materials. Our natural resources like timer, water, and minerals will be able to be revalidated.When it comes to saving energy, it will help to reduce the greenhouse gas emissions that are apart of the climate change. The main goal is also to help us to sustain the environment for generations to come. The Job market also depends on recycling centers for paying Jobs in that community. There is one question we can ask ourselves. â€Å"Are we throwing away an energy solution? † If we were to burn all the waste in the landfills of the US, it would provide an extra 33 gateways-which is the equivalent of 33 large power plants. Philipp Schmidt-Pitchman) We are missing out on a viable energy source to help us to not to depend on other countries for our natural resources. Many Americans still believe that burning trash gives off toxic fumes but, with how modern waste-to-energy factorie s process it, there is very little air pollution. How it works is that the high temperatures burn off the bonds of toxic chemicals. I use many plastic container for storing craft materials as a way to recycle. We take any egg cartons to the farms that sale eggs. Recycling Recycling: The Best Savings Plan for a Better Tomorrow. Recycled Orchestra is the orchestra which consists of kids and teenagers who play music with the help of recycled instruments in Cateura, Paraguay which a slum made on a landfill. The people in the slums cannot afford to buy musical instruments for their children. So, they collect the instruments and waste items from the garbage and by repairing the instruments and using the other required things to make the instruments for their children.Thus, recycling of the broken instruments had led to an orchestra with an increasing number of participants in the group and which now competing in many of the tournaments in and out Paraguay. Recycled Orchestra is one of the best examples of recycling things with great output. This also shows that recycling the waste and trash into useful goods not only keeps the environment clean and saves money and raw materials but also help completing peoples dreams.Recycled Orchestra and Recycled business of games and other articles are some of the most popular concept of the biggest slums in the world. Recycling is the process of converting waste and materials into useful products to avoid the wastage of potentially useful resources, conserve the fresh raw resources for the future, reducing the pollution caused during the disposal of waste like the combustion of useless products and the activities like landfills which causes the contamination of soil and minerals and groundwater beneath it and basically to protect our planet from contamination.Recycling is one of the components of â€Å"Waste Hierarchy† –Reduce, Reuse and Recycle. Recycling is a huge topic to take into the picture the steps for recycling like collecting, sorting, processing and finally using the recycled waste into useful products, then comes in the things to be recycled which give the maximum output like paper, metals, water, glass and plastic these are some of the most important ones and finally the global issues like global warming, greenhouse gases and pollution which recycling provides a solution.Firstly, the steps for recycling consist of some of the basic steps like collecting, sorting and processing it into useful products. These steps induces the â€Å"Waste Hierarchy† by itself by collecting the waste and the recyclable material from the garbage it reduces the amount of the usage new and fresh material and also reduces the waste going for direct incineration or dumping. Reuse is the final step after recycle, which is acceptance from the consumers or the usage of recycled products.The collection process is taken care by the government by assigning central collection facility for various localities and areas which collect the waste and trash from different places such as drop-off centers, buyback centers and the curbside centers. The drop-off centers consists of the various utilities which help in the collection of the junk like the rubbish bin, the other public u sage trash bin and this rash consists of unknown stuff as these drop-off centers are located in public places where so people throw a lot of unwanted and unknown stuff.The buyback centers are the profit making organizations which charge customers for collecting their trash from their community and their houses and collect the trash and sorting it and selling the same trash to the recycling facilities and waste management centers. The other facility for trash collection is the curbside centers wherein the client separates their trash according to their knowledge prior to the curbside center’s trash collection vehicles come and pick up the trash. These vehicles then dump the trash directly to the central sorting facility.Sorting is one of the most important parts of the recycling process, because if the all the things in the trash are not properly sorted the important recyclable things or even simply repaired could go in vain as in the case of recycled orchestra wherein the pro cesses of sorting they find the broken instruments which by repairing save a lot of money and cleaning up the waste. The sorting process helps in proper recycling and decomposition as well. The recycling process goes through a lot of chemical and physical changes in the actual matter which is being processed.Thus, the mixture of two different matters might change in the final result and the whole process of recycling from the collecting till the end goes in vain and creating toxic waste. Sorting of easily recyclable materials such as metals, glass, paper and plastic are the most common ones. The sorting process is taken carry by the material recovery facility wherein his paper and metal waste is separated using the vibration method which brings the light items up like first paper, then plastic and finally metals and glass which are the heaviest.The steel items such as cans and bottles are sorted by the magnetic separation method. Then the aluminium and other metallic waste are sorte d by the electric current and the plastics by the sensors and finally the glass is taken out and using the scanner for glass is checked for any other materials except the glass and then passed for recycling. Thus this thing is finally given out for finally processes. The www. recyclingguide. k org website approved by the waste management organization gives information regarding recycling and some facts such as that Up to 60% of the rubbish that ends up in the dustbin could be recycled and this unused energy from the dustbin could light up a television for more than 5000 hours. After the sorting processes the sorted garbage or trash is taken to their particular recycling centers for recycling. Recycling processes in general consists of breaking the used things in to its basic structure and then again using it for as a new product.The recycling of paper consists of breaking down the paper by mixing it with water and other chemicals and once the solution of the liquidized form of paper is formed it then heat treated and finally converted into new paper. The Bureau of International Recycling suggests that the recycling of the paper can be done for at least 7 times with a small amount of degradation in the quality of paper. Recycled paper produces 73% less air pollution than if it was made from raw materials.It's always better to use a 1 ton of recycled paper than using 24 trees for making 1 on of newspaper. The other most important substance which is recycled is metals which if sorted properly would save a lot of fresh natural resources. The recycling of metal is done by melting the used and thrown out metals at high temperature which breaks the rigid grain structure of these metals and then these metals are heat treated and and formed into desired shapes but these recycled metals are not used for heavy duty purposes due to low factor of safety and durability in it.The vehicle waste which mainly consists of metals, around 80% 0f the vehicles can be recycled. The o ther metals and substance like lead, glass and plastic go through the same process of melting and breaking down the grain structure and heat treated and finally molded into substances of daily usage but not used at the same level. With an increase of usage of plastic at the rate of 4-8% per year throughout the world, recycling them is the best option and anyway decomposition of plastic takes around 500 years.The other form of waste and the most dangerous one is the toxic waste and the waste after recycling all the waste is usually dumped into the modern landfills and modern incinerators. The landfills are big pits wherein the toxic waste and the non degradable waste is stored for decomposition. The decomposition takes place with the help of the chemicals and bacterias added in the landfills which increase the rate of the disintegration and lead to the formation of one of the most toxic gas which is methane more harmful to the environment than carbon monoxide.This gas is collected fr om the top of the the landfill through a suction pipe and then supplying methane to the thermal power plants near by to produce electricity. Some of the examples of landfills like the Cateura, Paraguay in the illustrations and another famous example is the Olympic Grounds in Australia wherein a lot of toxic waste like tanks and old warships is dumped Olympic grounds. The other types of landfills are for the human waste such as Biogas plant, Digestor which are usually implemented in the rural areas for the production of biogas to cook food and heat the house.These are big vessel or container of human and agricultural waste which is mixed with water and this solid-liquid mixture known as slurry is dumped into the digestor or the vessel and an electronically operated stirrer is provided to mix the slurry from time to time. The slurry is then kept in the digestor for a couple of weeks and due to which there is an increased in the temperature up to 70 °C – 80 °C in the vessel due to the decomposition and this induces the production of butane gas which useful in cooking and heating the house.The left out in the bioreactor known as the sludge is used as fertilizer for agriculture. Generally, biogas plant was popular in the rural areas only but nowadays there are being taken into account due to urge of renewable energy. One of the world largest biogas plant is the Penkun biogas park which has 40 modules of 500 kW electrical power each, digesting mainly energy crops. The thermal energy produced is used in a fertilizer factory next to the biogas park which is situated in Germany.Finally, if the recycling doesn’t work, incineration is the only way by which this non- recyclable byproduct cannot be used but vanished. The biomass from this landfills and biogas plant is usually used as fertilizer but the toxic ones are usually incinerated in the modern high temperature incinerator which incinerate both the liquid and the solid waste at really high temperatu res. This high temperature incineration is the â€Å"Best Technology Available† as quoted by the Mitchell Young, the editor of the book Garbage and Recycling as determined by the EPA.Most of the big factories have their modern hazardous waste incinerator on –site in their factory. But the small business depends on the off-site incineration managing all the hazardous wastes. These incinerators operate at high temperature around 1800 °F. The incinerator consists of a primary combustion chamber, an afterburner or the secondary combustion chamber which is connected to the pollution control system for controlling a monitoring the process.The afterburner increases the temperature form 1800 °F to 2200 °F which completely converts the hazardous solid and liquid waste into ashes or gases. The big banner companies such as Dove, Reliance and many more production hubs like it. But it always better to recycle than to incinerate which at some point pollute the environment. Thi s all will help in solving the global issues like global warming, pollution, greenhouse effects and many more and reduce his usage of fresh and raw resources for future. To conclude this, Recycling waste is a long term project.But its key lies in segregation and putting in some efforts to clean up the neighborhood. The main motto of recycling is creating zero waste which a worthwhile goal. If the process of recycling starts from the waste producer then it becomes much easier to recycle the process like sorting the waste and avoiding the non-recyclable material out of the landfills and dumps. Thus,recycling said to be a process not a step. These awarenesses in the people would help in achieving the goal of zero waste. Recycling is equal to a better, healthier savings plan for tomorrow.

Monday, September 16, 2019

Of Mice And Men coursework (Theme Of Loneliness And Friendship) Essay

Consider the theme of loneliness in ‘Of Mice and Men’. How does it affect the friendships and relationships in the novel? This novel was written by John Steinbeck which was set in the 1930s in Salinas Soledad which is in California. The novel consists of many historical factors which have affected the characters in this novel and one of them includes, â€Å"The great depression† Which leads the novels inspiration for the famous writer John Steinbeck which he mainly based on his own experience. In those days people travelled a lot differently to how we travel now. In those days migrant workers travelled extravagant distances looking for a job. There are many different themes in which are based throughout the whole book, such as loneliness, happiness, nature, dreams and reality: – Which even lead to catastrophe. Many of the people in this novel have very lonely lives mainly because they are migrant workers and as we know they don’t have time to make an y friends or have any time to spend with their families. There are many characters that are lonely due to age, sex, and race. Two good examples would be Candy because of his age and Crooks because of his race. This novel consists of two main characters George and Lennie, who are an anomalous pair of migrant workers that look after each other. They are completely the reverse of each other. George is the one who has the communicative face and thinks of all of their problems and ideas and tells the other one what to do. Being like this all of the time, in what ever the story it is, always pictures that you would be the small quick one with sharp features. Lennie is the guy that is tall and always does what he is told and has an ill-defined, solid, and powerful body and does not know his own strength. Steinbeck describes him as the one with no shape in his face and his body. Lennie drags his feet when he walks and acts like an animal. In the descriptions of these two men their appearance is completely different. George dresses neat and tidy, while Lennie dresses very scruffy. Just by the description of George and Lennie, you can clearly see that Lennie is the child out of the two men, as you can tell how he talks and acts around George and throughout the whole book. Being a man Lennie lacks a lot of language, which I think that he never attended a lot of school. Examples â€Å"look George, look what I done!† this is immature language. This kind of behaviour makes George the father type figure, so he would be the defender. John Steinbeck relates to Lennie, in the theme of nature, by describing his walk, and some of the things he does in relation to the animals like the way he drinks from the lake as Steinbeck describes him as a horse that puts its whole head into the water and slurps. This links in to the theme of natures, because of the use of animal descriptions that Steinbeck uses throughout the book, which is very important to this novel because in the beginning of the book, Nature was introduced straight away. Steinbeck’s describes the surroundings in such detail, that he uses a whole page to describe the forest (which is in the beginning of the book) which gives the readers a good imaginative view of what Steinbeck is writing. George and Lennie have an abnormal relationship. They are two friends, one needs the other more .George often gets very frustrated towards Lennie, which also shows that George cares. George loves Lennie very much and will always be a friend to him and so does Lennie. Lennie could not live without him because George does everything for him. Between George and Lennie, George is the one that is mainly in control, he cooks, finds them jobs finds them a place to sleep and because of this, they always travel together, where one goes, the other one follows like a duck and her ducklings. George travels with Lennie because Lennie would not be able to survive on his own. These two men share the same dreams but George knows in reality, it is not going to happen. Later on in the story Candy has now been introduced to the book as the old swapper. He is tall, stooped shoulders and has white whiskers. When you first see him, he is very friendly, although he is a little weary of newcomers. His only friend is his dog that he has had since he was a little boy which symbolises that he is very lonely which refers to the theme of loneliness. When he gets to know people, he begins to trust them; he opens up and strikes a conversation with his new friends just as he did with Lennie. A little further on in the story as they become very close together and even share each others dream. In the future he looses both his dog and Lennie and can’t really prevent Lennie’s death but tries to prevent his dog’s death, but this fails. This shatters Candy’s dreams because he cannot share his dream with his long companion. In Chapter 4, Crooks is introduced. He is the only coloured (black) person on the ranch and this is where the theme of loneliness comes into play. Crooks is a stable buck. He has a crooked spine, and his eyes lay deep in his head, he is lined with deep black wrinkles and has thin tightened lips. Again relating to the theme of loneliness, Crooks lives by himself in a shed because he is the only Black man, this is why he can afford to leave all of his belongings lying around. He has got his own collection of items like books, shoes and his own copy for the California civil code which indicates that he knows his rights and does not want to be taken advantage of. Eventually Crooks and Lennie are talking about if Lennie could live without George and about crook’s childhood explaining why his father never let him play with other kids and why he is so lonely. When he is speaking with Lennie about his childhood, he is speaking like it is still happening or it has recently happened. This is a very similar story to his life at that present time. Being the only coloured man, Crooks is treated as an outcast, as racism was very high in those days which forces him to spend his time reading while the others are playing card games. Crooks become very bitter due to the fact that everyone ill treats him which makes him feel hurt. In the next chapter Curley is introduced to the story. He is the boss’s son, he has a wife, she has dark hair that reaches down to her shoulders, her eyes are quiet close together and has pink small lips with very pale skin. The book does not mention anything about her name which suggests that she does not know who her parents are and does not have an identity. She behaves like she is not Curley’s wife and that she is single so she flirts with a lot of the men behind Curly’s back. She would say things like â€Å"now that we’re alone what do you want to do†. To try and tempt the man. In doing this, all the men try as hard as they can to stay away from her because they know that she is trouble and know how Curley feels about his wife. Curley’s wife does this because she wants attention, again, related to the theme of loneliness. All the farmers speak really bad of her because of her being flirtatious they also are frightened to talk to her because they fear Curley, and he would think that something is going on; plus he has the authority to get them fired or to shoot them. She married Curly to get some sort of status and to have an identity but she never liked him anyway. When she describes her life on the ranch, she says that her life is boring, that no one pays any attention to her and that she gets treated like a little girl. Curley’s wife often dreams about herself becoming an actress. At the end of the novel, her loneliness causes Lennie’s death. Before Lennie’s death, Curley’s wife and Lennie were talking in the barn whilst everyone else was playing games. They began talking to each other about each others dreams. They both talked about each others dreams and what they wanted to do in their life. Lennie has a fascination of stroking things. He was stroking Curley’s wife’s hair, he began to stroke her hair so hard, that he lost control and broke her neck. This has a big impact on George, Lennie and Candy’s relationship, as Curley wants to kill Lennie. As a result to this, George has to kill Lennie before he gets killed by Curly. Loneliness will always end in tragedy and dreams will rarely become reality. True Friendship never ends.

Sunday, September 15, 2019

Extraction and Evaporation Recrystallization Essay

1. To the components of a simulated pharmaceutical preparation, Panacetin, and identifying the unknown component of the mixture through extraction and separation methods. 2. To learn how to purify by recrystallization, how to dry them and how to obtain a melting point. PRECAUTION: ACETANILIDE AND PHENACETIN ARE EYE AND SKIN IRRITANTS. Minimize contact with your unknown compound. THEORY: In this experiment, Panacetin, a pharmaceutical preparation will be separated from its components by making use of their solubilities and acid-base properties. Panacetin contains aspirin, sucrose and an unknown component that may be either acetanilide or phenacetin. Of the three components, only sucrose is insoluble in the organic solvent dichloromethane (CH2Cl2 or methylene chloride). The insoluble sucrose can be filtered out if Panacetin is dissolved completely in dichloromethane by gravity filtration or centrifugation leaving the soluble aspirin, acetanilide and phenacetin in the solution. Although the acetanilide and aspirin are both quite insoluble in water at room temperature, the sodium salt of aspirin is very soluble in water but insoluble in dichloromethane. Aspirin, which is a strong acid can be converted to the salt, sodium acetylsalicylate by extraction with an aqueous solution of sodium bicarbonate . This salt will migrate from the dichloromethane layer, in which it is insoluble, to the aqueous layer, in which it is soluble. The unknown component will stay behind in the solution  and can be isolated by evaporating the solvent from the dichloromethane solution. Adding HCl to the aqueous solution restores aspirin as an insoluble white solid. In the third experiment, the identity of the unknown component of Panacetin will be purified. Purification is necessary because the separation procedure may be imperfect leaving traces of small quantities in the compound after separation or chemical reactions may occur prior to or during the separation adding new impurities. The unknown component can be purified by recrystallization, in which an impure solid dissolves in a hot (usually boiling) solvent then crystallizes from the cooled solution in a purer form. METHODS/PROCEDURES: This experiment was followed from the textbook on pages 52-53 for experiment 2 and 59-60 for experiment 3 excluding the microscale part. First, weigh approximately 3.00 g of Panacetin and transfer it to a clean, dry 125 ml Erlenmeyer flask. Add 50 ml of dichloromethane to the flask , stir the mixture with a stirring rod to break up any lumps. When it appears that no more of the solid will dissolve, filter the mixture by gravity. Collect the undissolved solid on the filter paper and set it aside to dry. Once it has completely dried, reweigh the solid. This compound separated by gravity  filtration is known as sucrose. Next, transfer the filtrate to a separatory funnel and extract it with two 30 ml portions of 5% sodium bicarbonate . For each extraction, use a stirring rod to stir the liquid layer until any fizzing subsides before a stopper is placed on the funnel and shaken. Dichloromethane will be on the bottom layer and will be drained to a different container. Transfer the dichloromethane layer back into the funnel for the second extraction. The upper layer will be transferred in an Erlenmeyer flask and will be used for recovery of acetanilide. Combine the two aqueous solutions in the same container and acidify slowly with 6M HCL to bring it to a pH of 2. Cool the mixture to room temperature or below while swirling the flask occasionally in an ice bath. Collect the aspirin by vacuum filtration. Wash the aspirin on the filter with cold distilled water. Dry the sample thoroughly before weighing and leave it in the hood for the next lab schedule. Before proceeding to recrystallization, triturate the compound with 20 ml of hexane. Crush the solid with a stirring rod and filter. Recrystallize the unknown drug component from experiment 2 by boiling it with just enough water to dissolve it completely, then letting it cool to room temperature then to 0 C. In order to induce crystallization, it would be helpful to scratch the walls of the flask so that crystals would have a surface to attach to. Use vacuum filtration to isolate the sample then dry the product to a constant mass and weigh in a tared vial. Grind a small amount of the dry unknown component to a fine powder on a watch glass using a spatula. Divide the solid into four equal portions. Combine portions 1 and 2. Mix portion 3 with an approximately equal amount of finely ground acetanilide and mix portion 4 with an approximately equal amount of finely ground phenacetin. Obtain the melting point ranges of the purified unknown (portions 1 and 2), mixture with acetanilide and mixture with phenacetin. Each melting point should be measured on two samples- more than that if melting points are imprecise or accurate. Safety Issues: (all of these are taken from MSDSonline.com) 1. Acetanilide Potential Acute Effects: Hazardous in case of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant). Potential Chronic Health Effects: Hazardous in case of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant). 2. Phenacetin Eye and skin irritant 3. Dichloromethane Potential Health Effects Inhalation: Causes irritation to respiratory tract. Has a strong narcotic effect with symptoms of mental confusion, light-headedness, fatigue, nausea, vomiting and headache. Causes formation of carbon monoxide in blood which affects cardiovascular system and central nervous system. Continued exposure may cause increased light-headedness, staggering, unconsciousness, and even death. Exposure may make the symptoms of angina (chest pains) worse. Ingestion: May cause irritation of the gastrointestinal tract with vomiting. If vomiting results in aspiration, chemical pneumonia could follow. Absorption through gastrointestinal tract may produce symptoms of central nervous system depression ranging from light headedness to unconsciousness. Skin Contact: Causes irritation, redness and pain. Prolonged contact can cause burns. Liquid degreases the skin. May be absorbed through skin. Eye Contact: Vapors can cause eye irritation. Contact can produce pain, inflammation and temporal eye damage. Chronic Exposure: Can cause headache, mental confusion, depression, liver effects, kidney effects, bronchitis, loss of appetite, nausea, lack of balance, and visual disturbances. Can cause dermatitis upon prolonged skin contact. Methylene chloride may cause cancer in humans. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders, eye problems, impaired liver, kidney, respiratory or cardiovascular function may be more susceptible to the effects of this substance. 4. Aspirin Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May be absorbed through skin and cause target organ effects. Inhalation: No health effects are expected. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. Repeated ingestion may cause: May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Prolonged or repeated exposure may cause: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Clotting Disorders: Signs/symptoms may include increased blood clotting time and internal bleeding (hemorrhage). Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred  speech, giddiness, and unconsciousness. Kidney Effects: Signs/symptoms may include reduced or absent urine production, increased serum creatinine, lower back pain, increased protein in urine, and increased blood urea nitrogen (BUN). Pulmonary Edema: Signs/symptoms may include chest discomfort, shortness of breath, significant cough with frothy sputum production, bluish colored skin (cyanosis), increased heart rate, respiratory failure and may be fatal. Single exposure may cause: Immunological Effects: Signs/symptoms may include alterations in the number of circulating immune cells, allergic skin and /or respiratory reaction, and changes in immune function. 5. Sodium Bicarbonate EMERGENCY OVERVIEW Warning! May cause respiratory tract irritation. Causes eye and skin irritation. Target Organs: Blood, kidneys, heart, liver, eyes, skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May be harmful if swallowed. Causes gastrointestinal tract irritation. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: May cause liver and kidney damage. Adverse reproductive effects have been reported in animals. Laboratory experiments have resulted in mutagenic effects. Chronic exposure may cause blood effects. 6. Hydrochloric Acid POTENTIAL HEALTH EFFECTS: Inhalation: May cause irritation (possibly severe), chemical burns, and pulmonary edema. Skin contact: May cause irritation (possibly severe) and chemical burns. Eye contact: May cause irritation (possibly severe), chemical burns, eye damage, and blindness. Ingestion: Not a likely route of exposure. Target Organs Effected: Respiratory System, Skin, Eye Chronic Effects: Repeated or prolonged exposure to dilute solutions may result in dermatitis. Discoloration of the teeth may occur as a result of long term exposure. Interaction with Other Chemicals Which Enhance Toxicity: None known Medical Conditions Aggravated by Exposure: None known OBSERVATIONS/RESULTS: In Experiment 2, the extraction of substances from one another is based on the differences in their physical and chemical properties. Approximately, 3.0029 g of panacetin was weighed and completely dissolved in 50 ml of dichloromethane and filtered. The residue was left to dry and weighed (sucrose). Then 30 ml of NaHCO3 was added to the filtrate. This solution was transferred into a separatory funnel. This formed two layers. Top layer was the organic layer (NaHCO3) described as a clear liquid. Bottom layer was the aqueous layer and was yellow in color. The filtrate was washed twice with NaHCO3. HCl was added to the aqueous solution until the pH equaled to 2.0. It was filtered through vacuum filtration and allowed to dry until the next week’s lab. This filtrate is known as aspirin. Meanwhile, the unknown in the organic layer was also allowed to settle for the next experiment. In experiment 3, before we went to do recrystallization, we first did trituration of the unknown by adding 20 ml of hexane. We crushed the solid and filtered. Even with the addition of approximately 27 ml of boiling water into the compound, it started to dissolve. That was the first clue that we have acetanilide as our unknown. We went ahead and continue heating and swirling the solution over a hot plate. There was the formation of brown oil-like globules. We were then asked to decant the clear liquid from this solution. This clear liquid was allowed to cool to room temperature then to 0 C. There was formation of white crystals at the edge of the beaker. Through vacuum filtration, we were able to filter the product, weighed and used for melting point measurement of the unknown. The solid was divided into 4 equal parts. First 2 parts were combined, 3rd part was mixed with acetanilide and the last part was mixed with phenacetin. After taking the melting points of all these 3 substances we were able to identify the unknown product to be acetanilide. No big issues encountered during this experiment. Transferring some products as well as the final crystals from watch glass and filter paper and leaving some products were crucial to get the most final product. This explains why the percent recovery for the unknown was low. Some crystals fell off or didn’t transfer to the filter paper. Even though the % recovery was relatively low (88.4079%), this experiment still produced a 0.6898 g of product. DISCUSSION/CONCLUSION: This experiment was focused on two main objectives. First, the analysis of panacetin to find out what percentages of sucrose, aspirin and the unknown component it contains. Second, to find out whether the unknown is acetanilide and phenacetin. A big part of the composition of panacetin was made up of the unknown. We were able to determine the composition of sucrose to be 17.95 %, Aspirin 26.93% and the unknown to be 55.12% After following the experiment procedures, we were able to purify through recrystallization the end product to be acetanilide. This is an odorless white crystalline solid substance which has a melting point of 114 C. Our experimental value for acetanilide’s melting point was 117 which indicates that the result had a very narrow range and close to the literature value. I would therefore conclude that we had isolated a close to pure product of acetanilide with little impurities present. 1. a. Describe any evidence that a chemical reaction occurred when you added 6 M HCl to the solution of sodium acetylsalicylate A chemical reaction took place upon the addition of 6M HCl to a solution of sodium acetylsalicylate because a precipitate formed known as aspirin. b. Explain why the changes that you observed took place. The observed change took place as a result of the acid reacting with the salt forming a compound insoluble in water. 2. Describe any explain the possible effect on your results of the following experimental errors or variations. In each case, specify the component (s) whose percentage(s) would be too high or too low. a. After adding dichloromethane to Panacetin, you didn’t stir or shake the mixture long enough Improper stirring or shaking of the mixture will result in incomplete dissolution of the panacetin mixture. There will be loss of some solid analytes during filtration. The recovered amounts will be lower than they should be leading to a final percentage to be low. b. During the NaHCO3 extraction you failed to mix the aqueous and organic layers thoroughly. If the aqueous and organic layers were not thoroughly mixed the acid would remain in the solution and the extraction would be less efficient resulting to a low percentage yield. c. You mistakenly extracted the dichloromethane solution with 5 % HCl rather than 5 % NaHCO3. If 5% HCl is used instead of 5% NaHCO3 that would protonate the aspirin and keep it in the organic solution making the aspirin, acetylsalicyclic acid. d. Instead of using pH paper, you neutralized the sodium bicarbonate solution to pH 7 using litmus paper At ph7 the bicarbonate wouldn’t be able to act as a base and extract a proton because at pH of 7 it would protonate itself so it wouldn’t be able to react with aspirin. 5. Write a balanced reaction equations for the reactions involved a. When aspirin dissolves in aqueous NaHCO3 C9H8O4 (aq) + NaHCO3 (aq) —–> C9H7O4Na (aq) + CO2 + H2O Weak acid weak base Strong Base Strong acid b. When Aspirin is precipitated from a sodium acetylsalicylate solution by HCL C9H7O4Na + HCl ————-ËÆ' C9H8O4 + NaCl Strong Base Strong acid Weak Acid Weak Base Assuming that both reactions are spontaneous under the standard conditions, label the stronger acid, stronger base, weaker acid and weaker base in each equation. Experiment 3 1. a. What is the minimum volume of boiling water needed to dissolve 0.200 g of phenacetin? b. About how much phenacetin will remain dissolved when the water is cooled to room temperature? c. Calculate the maximum mass of solid (undissolved) phenacetin that can be recovered when the cooled solution is filtered. 0.200 g-0.0125 g (amount soluble in cold water)= 0.1875 g 2. An unknown compound X is one of the four compounds listed in table 3.2. A mixture of X with benzoic acid melts at 89 C, a mixture of X with phenyl succinate melts at 120  °C and a mixture of X with m-aminophenol melts at 102  °C. Give the identity of X and explain your reasoning. X is phenyl succinate. When a compound mixes with a different compound, the melting point of the mixture will be lower than the melting points of either of the pure compounds. Basing from the table, the melting point of pure benzoic acid is 121 C but when mixed to X, it went down to 89 C. Likewise with O-toluic acid and m-aminophenol. Since the melting point of mixture X with phenyl succinate has a melting point of 120 C, the melting point of pure X must be equal or closer to 121. Mixing X with phenyl succinate did not change the melting point thus X must be phenyl succinate.